The role of neutralizers in reducing corrosion

Neutralizers
Neutralizers reduce corrosion by reducing the concentration of H+ ions in the solution. Neutralizers are even added to neutral solutions containing CO2 because the concentration of H+ ions is much higher at high temperatures due to the formation of carbonic acid. Neutralizers can control small amounts of hydrochloric acid, carbon dioxide, sulfur dioxide, hydrogen sulfide, and organic acids that may concentrate at points in the system and react with water to produce H+. Today, ammonia and caustic soda, which were used in steam boilers for many years, have been replaced by neutralizing amines. The table below lists some common types of neutralizers.
Inhibitors | Systems |
NH3 | Boilers, cooling water, fresh water, vapor phase |
Monoethanolamine | Glycol cooling systems |
Diethanolamine | Glycol cooling systems |
Borat | Glycol cooling systems (automobile) |
CaO | Fresh waters |
Cyclohexylamine | Vapor phase inhibitor |
Amylamine benzoate | Vapor phase inhibitor |
NaOH | Oil refining |
Na2CO3 | Oil refining |
Alkyl amines | Oil refining, crude oil production |
Polyamines | Oil purification, sour water (H2S) |
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